天然气水合物加热开采机理及数学模型     

王计堂 《地质与勘探》2012,48(1):185-190

在目前已有的主要水合物开采方法研究的基础上,进一步研究了天然气水合物加热开采法的机理。研究认为,水合物是加热分解、热传导和含化学分解的液、气两相渗流流动,它们之间既相互独立,又相互联系。并将水合物区划分为分解区和未分解区,将分解区前缘作为可移动的分界面,分区建立了加热分解热传导数学模型及含分解化学反应的液、气两相渗流流...  相似文献   

Research on thermal shock resistance of mullite-bauxite-silicon carbide castable refractory   总被引：1，自引：0，他引：1  

Nobuaki Chiyoda 《中国地球化学学报》2012,31(2):204-208

Effects of different silicon carbide contents on thermal shock resistance properties of mullite-bauxite castable refractory were analyzed respectively by taking the mullite,bauxite as main raw materials and taking calcium aluminate cement as a binding system.After 24 h curing in mould and another 24 h curing at 110℃ after demoulding,the samples were heated at 1000,1300 and 1500℃for 3 h in air,respectively.The bulk density,thermal expansion coefficient and thermal shock resistance were examined.The results showed that there was a great effect of content of SiC on bulk density,thermal expansion coefficient and thermal shock resistance of mullite-bauxite castable.Under the experimental conditions,the castable performed the best thermal shock resistance when w(SiC)=5%-10%.  相似文献   

微波照射下火成岩升温特性和升温预测模型研究     

赵沁华  赵晓豹  赵建新  刘汉文  郑彦龙  李建春  何磊  何举龙  余家旺 《高校地质学报》2021,27(1):94-101

微波辅助破岩可有效降低刀具磨损,提高破岩效率,具有广阔的发展前景。文章选取了10种火成岩进行微波加热试验,发现岩石的升温速率主要与岩石所含矿物的种类、含量,及岩石中的Fe元素含量有关。岩石所含矿物越敏感、含量越多,岩石中的Fe元素含量越大时,其升温速率越高。整体而言,火成岩中基性岩的升温速率最高、中性岩次之、酸性岩最低,该现象与火成岩的矿物和元素组成规律有关。在试验研究的基础上,文章提出了岩石升温预测模型。该模型除考虑了矿物种类和含量的影响外,还考虑了与升温有关的比例修正系数和结构修正系数。在升温预测模型中,敏感矿物升温的比例修正系数大于1,且随含量的增加而降低,最终趋向于1;非敏感矿物升温的比例修正系数小于1,且随含量的增加而增加,最终也趋向于1。同等条件下,块体的升温速率是粉末的2~3倍,且基性岩升温的结构修正系数大于中性岩和酸性岩。  相似文献   

冬季青藏高原大气热状况分析Ⅱ：年际变化   总被引：4，自引：3，他引：1  

宇婧婧  刘屹岷  吴国雄 《气象学报》2011,69(1):89-98

通过诊断3套再分析资料的非绝热加热场,研究冬季青藏高原上空大气的热力特征.结果表明,与夏季为强热源的特征不同,冬季高原上空不是欧亚大陆上最强的冷源中心.冬季高原上空整体是偏弱的冷源,在高原西侧及东南地区上空甚至出现非绝热加热正值区,这一分析对以往研究提出的高原是冷源的特性给出了修正.各种非绝热加热分量的诊断表明,冬季高原上空这种总的非绝热加热分布主要是由于高原主体的长波辐射冷却较周边地区弱,以及西侧至东南地区凝结潜热释放造成的.为了说明再分析的非绝热加热资料对冬季高原上空大气的这种热力特征描述的可信性,文中还利用了地表辐射能量、TRMM及PREC/L降水、垂直速度等资料进一步辅助分析,证实了由于高原位势较高造成大气整层温度偏低,向外长波辐射偏少,以及高原地势的隆起造成局地较强的上升运动,高原西侧至东南角降水大值区潜热偏大,最终造成高原上空总非绝热加热负值偏小.最后理想高原隆起的水球试验结果说明,冬季,高原的存在减弱了陆地上空的冷却效应,因而其上为弱冷源,再次证实了资料分析的结果.  相似文献   

Relationship Between the Western Pacific Subtropical High and the Subtropical East Asian Diabatic Heating During South China Heavy Rains in June 2005          下载免费PDF全文

WANG Lijuan  GAO Hui  GUAN Zhaoyong  HE Jinhai 《Acta Meteorologica Sinica》2011,25(2):203-210

Based on the daily NCEP/NCAR reanalysis data, the position variation of the western Pacific subtropical high (WPSH) in June 2005 and its relation to the diabatic heating in the subtropical East Asia are analyzed using the complete vertical vorticity equation. The results show that the position variation of the WPSH is indeed associated with the diabatic heating in the subtropical East Asian areas. In comparison with June climatology, stronger heating on the north side of the WPSH and relatively weak ITCZ (intertropical convergence zone) convection on the south side of the WPSH occurred in June 2005. Along with the northward movement of the WPSH, the convective latent heating extended northward from the south side of the WPSH. The heating to the west of the WPSH was generally greater than that inside the WPSH, and each significant enhancement of the heating field corresponded to a subsequent westward extension of the WPSH. In the mid troposphere, the vertical variation of heating on the north of the WPSH was greater than the climatology, which is unfavorable for the northward movement of the WPSH. On the other hand, the vertical variation of heating south of the WPSH was largely smaller than the climatology, which is favorable for the anomalous increase of anticyclonic vorticity, leading to the southward retreat of the WPSH. Before the westward extension of the WPSH in late June 2005, the vertical variation of heating rates to (in) the west (east) of the WPSH was largely higher (lower) than the climatology, which is in favor of the increase of anticyclonic (cyclonic) vorticity to (in) the west (east) of the WPSH, inducing the subsequent westward extension of the WPSH. Similar features appeared in the lower troposphere. In a word, the heating on the north-south, east-west of the WPSH worked together, resulting in the WPSH extending more southward and westward in June 2005, which is favorable to the maintenance of the rainbelt in South China.  相似文献   

Application of organic petrology and geochemistry to coal waste studies   总被引：1，自引：0，他引：1  

Magdalena Misz-Kennan  Monika J. Fabiańska 《International Journal of Coal Geology》2011,88(1):1-23

Coal wastes produced during mining activities are commonly deposited in nearby dumps. These wastes mostly composed of minerals and variable amounts (usually 20-30%) of organic matter start to weather immediately after deposition. Oxidation of the organic matter can lead to self heating and self combustion as a result of organic and mineral matter transformations. The degree of alteration depends on the properties of the wastes, i.e., the maceral and microlithotype composition of the organic matter and its rank.Alteration of wastes also depends on the heating history, i.e., the rate of heating, final heating temperature, duration of heating, and the degree of air access. Although air is probably necessary to initiate and drive the heating processes, these usually take place under relatively oxygen depleted conditions. With slow heating, color of organic matter particles changes, irregular cracks and oxidation rims develop around edges and cracks, and bitumen is expelled. As a result, massive and detritic isotropic and strongly altered organic matter forms. On the other hand, higher heating rates cause the formation of devolatilization pores, oxidation rims around these pores and along cracks, vitrinite-bands-mantling particles, and bitumen expulsions.Organic compounds generated from the wastes include n-alkanes, iso-alkanes, alkylcyclohexanes, acyclic isoprenoids, mainly pristane, phytane and, in some cases, farnesane, sesquiterpanes, tri- and tetracyclic diterpanes, tri- and pentacyclic triterpanes, and steranes, polycyclic aromatic hydrocarbons (mostly with two- to five rings, rarely six rings), and phenols. The compounds formed change during the heating history. The fact that phenols are found in dumps where heating has not yet been completed, but are absent in those where heating ceased previously suggests the presence of water washing. The organic compounds formed may migrate within the dumps. However, when they migrate out of the dumps, they become a hazard to environment.This paper is a review on transformations of organic matter (both maceral composition and reflectance and chemical composition) in coal wastes deposited in coal waste dumps. Immediately after deposition the wastes are exposed to weathering conditions and sometimes undergo self heating processes.  相似文献   

辽西建昌盆地义县组上部英安岩的40Ar/39Ar年龄及其地质意义     

郑月娟  李永飞  郜晓勇  苏飞 《地质与资源》2011,20(3):167-171

建昌盆地义县组可分为两部分:下部以巨厚的沉积层为主,自下而上称为要路沟层、罗家沟层,局部地区沉积层之下有中基性火山岩;上部(罗家沟层之上)为酸性、中酸性火山岩系夹沉积层.罗家沟层与义县一北票地区尖山沟(砖城子)层可进行生物地层学对比.对义县组上部的一件英安岩样品进行40Ar/39Ar年代学研究,获得年龄为120 Ma,...  相似文献   

2003年夏季华南持续高温天气过程及热力诊断   总被引：4，自引：0，他引：4  

方宇凌  简茂球 《热带海洋学报》2011,(3)

利用华南观测的逐日最高气温资料和NCEP逐日再分析资料,对2003年6月29日—8月15日华南持续高温过程的大气环流背景、动力和热力条件进行了诊断分析。结果表明,2003年6月29日—8月15日华南大范围持续高温的前2段高温峰期与副高有关,第3段高温期大陆高压有关,而且3次高温过程都与热带气旋外围下沉气流有密切联系,而前2次持续高温的缓解都与热带气旋登陆和影响华南地区有密切联系。热力诊断发现,3段持续高温期间,近地层大气的局地增温主要是由非绝热加热作用(白天地表感热通量和地面长波辐射加热)造成的,水平温度平流对局地增温作用有负贡献。高温天气过程的晴空少云天气背景有利于白天太阳辐射加热地面,并可造成明显的地面感热通量和地面长波辐射加热近地面层大气,从而导致了持续高温天气过程。  相似文献   

华南区域降温度日和采暖度日的时空变化特征   总被引：1，自引：0，他引：1  

李艳兰  何如  杜尧东  陆虹 《热带地理》2011,31(1):14-20

利用华南区域110个气象站1961-2008年逐日平均气温资料,计算华南区域各地年降温度日和采暖度日,分析降温度日和采暖度日的时空变化特征,探讨度日与年平均气温的关系.结果表明:华南区域年降温度日具有南部大、北部小,河谷平原大、山区小的地域分布特点;年采暖度日则是由南向北增大.1961-2008年华南区域年降温度日呈现...  相似文献   

华南沿海2011年7月15—18日持续暴雨过程中的季风槽与中尺度对流系统相互作用   总被引：1，自引：0，他引：1  

蒙伟光  张艳霞  袁金南  李春晖  梁巧倩  吴乃庚 《气象学报》2014,72(3):508-525

应用NCEP FNL再分析资料及位涡分离反演等方法,对华南沿海2011年7月15—18日持续暴雨过程中季风槽与中尺度对流系统的相互作用进行了研究,主要针对暴雨发生期间季风槽气旋性涡度向上发展的机理及其对季风槽维持发展和中尺度对流系统活动的影响进行分析。结果发现,季风槽的中尺度对流系统发展于弱斜压性环境中,大多在槽东西两端涡度中心区发展最强。南侧盛行的西南低空急流为对流反复发生提供了对流发展的“可维持性”条件,是对流得以组织发展成为中尺度对流系统的重要原因。涡度收支诊断表明,季风槽气旋性涡度生成主要由中尺度对流系统低层辐合引起。位涡分离反演结果证实,季风槽气旋性环流增强主要由与中尺度对流系统潜热加热相关的扰动位涡造成,并随着中尺度对流系统加热峰值高度升高而向上发展,是大尺度环流对中尺度对流系统潜热加热动力响应的结果。在季风槽东西两端,由于中尺度对流系统发展强烈且持续,具有更高的加热效率,引起的气旋性涡度向上发展最为明显。其结果可引起中尺度对流系统西南一侧向北非地转风发展,并在地转偏向力作用下增强西风,维持低空急流的发展,为对流反复发生提供条件。这些都说明季风槽大尺度环流与中尺度对流系统相互作用在中尺度对流系统和持续暴雨形成过程中有重要作用。  相似文献